How to Change the Default File Format in LibreOffice

By default, LibreOffice saves files in the Open Document Format (ODF). However, it also reads and writes files in Microsoft Office formats (DOC and DOCX). If you collaborate with others on Microsoft Office documents, but you use LibreOffice, you can choose to always save files as Microsoft Office files to make it easier to exchange those documents back and forth.

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via: howtogeek.com